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العنوان
Preparation of Pd-based metal oxide electrocatalysts and their applications in the electro-oxidation of ethanol in alkaline medium /
الناشر
Ahmed Eslam Fahim Abdelatty ,
المؤلف
Ahmed Eslam Fahim Abdelatty
هيئة الاعداد
باحث / Ahmed Eslam Fahim AbdelAtty
مشرف / Randa Mohammed Abdelhameed
مشرف / Nageh Khalaf Allam
مناقش / Hayman Hassan Rehan
تاريخ النشر
2019
عدد الصفحات
95 P. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Chemistry (miscellaneous)
تاريخ الإجازة
30/7/2019
مكان الإجازة
جامعة القاهرة - كلية العلوم - Physical Chemistry
الفهرس
Only 14 pages are availabe for public view

from 157

from 157

Abstract

Core-shell structured M@Pd/SnO₂-graphene (Gr), [M = Co, Ni or Cu] electrocatalysts were synthesized using ethylene glycol as a reducing agent with the aid of microwave irradiation in a two-step process. XRD, TEM and EDX analysis techniques were employed to physically characterize the prepared electrocatalysts. They revealed the formation of SnO₂Gr as a support, surrounded by M as a core that coated with Pd as a shell. Cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy were employed to investigate the electrocatalytic activity of prepared electrocatalysts for ethanol oxidation in NaOH solution. chronoamperometry test demonstrated enhanced electrochemical durability for fabricated core-shell structured electrocatalysts. Lowered charge transfer resistance values were also measured at these electrocatalysts during ethanol oxidation reaction