الفهرس | Only 14 pages are availabe for public view |
Abstract This thesis comprises five chapters. The first is the introduction which reviewed the recent methods in the literature for synthesis and reactions of Methyl 4,6-O-benzylidene-α-Dglucopyranoside from carbohydrate precursors.The second chapter involves a detailed discussion of the results obtained by the candidate throughout the work; in which methyl 4,6-O-benzylidene-α-D-glucopyranoside 80 was prepared.Acetylation of 80 with a mixture of acetic anhydride and pyridine furnished the 4,6-O.81 diacetate-2,3 glucopyranoside-D-methyl-α-benzylidene 82 diol-2,3 glucopyranoside-D-methyl-α-benzylidene-O-4,6 gave 80 Periodate oxidation of Condensation of the diol 82 with a number of acylhydrazines in acidic medium +glucopyranoside 83,methyl-4,6-O-benzylidene-3-deoxy3-(p-chlorophenylazo)-α-Dglucopyranoside 84,methyl -4,6-O benzylidene-3-deoxy3-(p-methylphenylazo)-α-Dglucopyranoside 85 and methyl -4,6-O-benzylidene-3-deoxy. |