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Abstract Thethesisconsists of three main chapters. Chapter I is the introduction, chapter II represents ;heexperimentaltechniques, and chapter III contains the results and their discussion. ChapterI: In this chapter, an introduction was given which deals with the following fields of interest: polymerization and classification of polymers, conjugated polymers, oxidative polymerization, mechanism of electrpolymerization, electrochemical techniques of electropolymerization, cyclic voltammetry, electrochemical nature of steel corrosion, forms of corrosion of stainless steel, potential of zero charge, conductive polymer for corrosion protection, and literature survey on the protective effect of electropolymerized film on the corrosion of stainless steel. The aim of the work was also given in this part. Chapter 11:The main contents of this chapter were the experimental techniques used in the present investigation, which includes: Cyclic voltammetry technique is used for preparation of poly o-aminobenzoic acid electropolymerized film on the surface of stainless steel. Potentiodynamic polarization for corrosion measurements of uncoated and poly 0- aminobenzoic acid-coated stainless steel have been investigated. The detailed description of electrodes, solutions, cell, and experimental procedure were also given. Chapter Ill: In this chapter the experimental results were discussed in three parts: Part I: represents the electropolymerization of o-aminobenzoic acid on SS321 surface using cyclic voltammetry in 0.1 M H2S04 acid solution and 10% dimethylfonnamide using different scan rates, cycle number, and concentration of monomer. Effect of temperature on the polymer formation was also studied. The results showed that: • As cycles number increased, the height of the oxidation peaks increased regularly, which implied that the polymer was being well deposited onto the working electrode and that the thickness gradually increased. • The suitable scan rate required for electropolymerization process in 0.1 M H2S04 solutioncontaining 10% dimethylformamide is ranged from 1500-1800 mVImin. |